Robert D. Pike

Publications 1993-2009 (William and Mary student names underlined)

42) A. Saxena , E. C. Dugan, J. Liaw, M. D. Dembo, and R. D. Pike, "Copper(I) Complexes of Hetercyclic Thiourea Ligands", Polyhedron 2009, submitted.

41) A. G. Zestos , C. L. Grinnell, L. J. Vinh, R. D. Pike, and W. H. Starnes, Jr. "Metal-Exchanged Clay and Zeolite Additives as Smoke Suppressants and Fire Retardants for Poly(vinyl chloride)" Journal of Vinyl and Additive Technology 2009, 15, 87.

40) R. D. Pike, T. J. Brewster, and C. A. Bayse, "Photoluminescence of Copper(I) Cyanide Chains: A Theoretical Description", Inorganic Chemistry 2009 , 48, 174.

39) J. E. Kuperstock , A. N. Ley, and R. D. Pike, "Piperazinium Chlorocuprates", Journal of Chemical Crystallography 2009, 39, 131.

38) M. J. Lim , C. A. Murray, T. A. Tronic, K. E. deKrafft, A. N. Ley, J. C. deButts, R. D. Pike, H. Lu, and H. H. Patterson,  “Copper(I) Cyanide Networks: Synthesis, Structure and Luminescence Behavior , Part 2. Piperazine Ligands and Hexamethylenetetramine”, Inorganic Chemistry 2008 , 47, 6931.

37) A. Saxena and R. D. Pike, "Hydrogen-Bonding Networks in Heterocyclic Thioureas", Journal of Chemical Crystallography 2007, 37, 755.

36) T. A. Tronic , K. E. deKrafft, M. J. Lim, A. N. Ley , and R. D. Pike, “Copper(I) Cyanide Networks: Synthesis, Luminescence Behavior and Thermal Analysis, Part 1. Diimine Ligands”, Inorganic Chemistry 2007, 46, 8897.

35) S. B. Kim, S. Lotz, S. Sun, Y. K. Chung, R. D. Pike, and D. A. Sweigart, “The Synthesis and Application of Manganese Tricarbonyl Transfer (MMT) Agents”, Inorganic Syntheses , in press.

34) R. D. Pike, K. E. deKrafft, A. N. Ley, and Tristan A. Tronic “Threaded Structure and Blue Luminescence of (CuCN)20 (Piperazine) 7”, Chemical Communications 2007, 3732.

33) E. C. Dugan and R. D. Pike, “1,2,3,4-Tetrahydroquinoxaline”, Acta Crystallographica Section E 2007, o2772 .

32) R. D. Pike, M.-J. Lim , E. A. L. Willcox, and T. A. Tronic, “Nickel(II) and Cobalt(II) Nitrate and Chloride Networks with 2-Aminopyrimidine”, Journal of Chemical Crystallography, 2006, 36 , 781.

31) A. B. Wiles and R. D. Pike, “Copper(I) Chloride Carbonyl Polymers”, Organometallics 2006, 25, 3282.

30) R. D. Pike, A. B. Wiles , and T. A. Tronic, “bis(Thiophene-2-carboxaldehyde thiosemicarbazonato)diacetonitriledicopper(I) Tetrafluoroborate”, Acta Crystallographica Section E, 2006, 62, m347.

29) A. B. Wiles, D. Bozzuto, C. L. Cahill, and R. D. Pike, “Copper (I) and (II) Complexes of Melamine”, Polyhedron 2006, 25, 776 .

28) R. D. Pike, “Thallium: Organometallic Chemistry” In Encyclopedia of Inorganic Chemistry 2; R. B. King, Ed.; John Wiley and Sons: Chichester , U.K. , 2005, vol. IX, pp. 5569–5581.

27) L. M. Nguyen, M. E. Dellinger, J. T. Lee, R. A. Quinlan , A. L. Rheingold, and R. D. Pike, “Convenient Synthesis of Copper(I) Thiolates and Related Compounds”, Inorganica Chimica Acta, 2005 , 358, 1331.

26) R. D. Pike, B. A. Reinecke , M. E. Dellinger, A. B. Wiles, J. D. Harper , J. R. Cole, K. A. Dendramis , B. D. Borne , J. L. Harris, and W. T. Pennington, “Bicyclic Phosphite Esters from Pentaerythritol and Dipentaerythritol: New Bridging Ligands in Organometallic and Inorganic Chemistry”, Organometallics, 2004 , 23, 1986.

25) R. D. Pike, “Inorganic Additives for Polymers”, guest editorial, Journal of Vinyl and Additive Technology, 2004, 10, 1.

24) W. H. Starnes, Jr., R. D. Pike, J. R. Cole, A. S. Doyal , E. J. Kimlin , J. T. Lee, P. J. Murray , R. A. Quinlan , and J. Zhang , “Cone Calorimetric Study of Copper-promoted Smoke Suppression and Fire Retardance of Poly(vinyl chloride)”, Polymer Degradation and Stability 2003, 82, 15.

23) J. R. Cole, M. E. Dellinger, T. J. Johnson, B. A. Reinecke, R. D. Pike, W. T. Pennington, M. Krawiec, and A. L. Rheingold,  “Caged Phosphite Complexes of Copper(I) Halides”, Journal of Chemical Crystallography , 2003, 33, 341.

22) J. T. Maeyer, T. J. Johnson, A. K. Smith, B. D. Borne , R. D. Pike, W. T. Pennington, M. Krawiec, and A. L. Rheingold, "Pyrimidine, Pyridazine, Quinazoline, Phthalazine, and Triazine Coordination Polymers of Copper(I) Halides”, Polyhedron2003, 22 , 419.

21) R. D. Pike, B. D. Borne , J. T. Maeyer, and A. L. Rheingold,  “1,3,5-Triazine Templated Self-Assembly of a Hexameric Copper(I) Chloride Triphenyl Phosphite Core”, Inorganic Chemistry 2002, 41 , 631.

20) R. D. Pike, P. M. Graham , K. A. Guy, T. J. Johnson , J. R. Cole , S. M. Stamps, and L. E. Klemmer ,  “Network Complexes of Copper(I) Halides”, Journal of Chemical Education 2001 , 78, 1522.

19) R. D. Pike, W. H. Starnes, Jr., J. R. Cole, A. S. Doyal , P. M. Graham , T. J. Johnson, E. J. Kimlin , and E. R. Levy , “New Copper Complexes as Potential Smoke Suppressants for Poly(vinyl chloride)” In Fire and Polymers ; G. Nelson, C. A. Wilkie, Eds.; A.C.S. Publications: Washington, D.C., 2001; pp. 267-280.

18) R. D. Pike, W. H. Starnes, Jr., and P. M. Graham, “Copper(I) Networks: Potential Smoke Suppression Agents in Poly(vinyl chloride)” In Specialty Polymer Additives: Principles and Applications ; S. Al-Malaika, A. Golovoy, C. A. Wilkie, Eds.; Blackwell Science: Oxford, U.K., 2001; pp. 343-357.

17) P. M. Graham, R. D. Pike, M. Sabat, R. D. Bailey, and W. T. Pennington, “Coordination Polymers of Copper(I) Halides”, Inorganic Chemistry 2000, 39, 5121.

16) R. D. Pike, W. H. Starnes, Jr., and G. B. Carpenter, “Cubane Tetrameric Complexes of Copper(I) Chloride and Bromide with Triphenyl Phosphite”, Acta Crystallographica, Section C 1999, 55, 162.

15) R. D. Pike and D. A. Sweigart, “Electrophilic reactivity of coordinated cyclic p -hydrocarbons”, Coordination Chemistry Reviews 1999 , 187 , 183.

14) S. C. Chaffee, J. C. Sutton, C. S. Babbitt, J. T. Maeyer , K. A. Guy, R. D. Pike, and G. B. Carpenter,  “Improved Synthesis of [Mn(CO)OClO3], a Versatile Reagent for the Preparation of Cationic (Polyene)manganese(I) Complexes. Crystal Structure of [( h4 -1,5-Cyclooctadiene)Mn(CO)]ClO 4 ”, Organometallics 1998, 17, 5586.

13) R. D. Pike, W. H. Starnes, Jr., J. P. Jeng, W. S. Bryant , P. Kourtesis , C. W. Adams, S. D. Bunge , Y. M. Kang , A. S. Kim , J. H. Kim , J. A. Macko , and C. P. O'Brien , “Low-Valent Metals as Reductive Cross-Linking Agents: A New Strategy for Smoke Suppression of Poly(vinyl chloride)", Macromolecules 1997, 30, 6957.

12) M. P. Castellani, N. G. Connelly, R. D. Pike, A. L. Rieger, and P. H. Rieger, “EPR Spectra of [Cr(CO) 2L( h -C 6 Me6)]+, L = PEt 3 , PPh 3 , P(OEt) 3, P(OPh) 3 : Analysis of Line Widths and Determinations of Ground State Configuration from Interpretation of 31P Couplings”, Organometallics 1997, 16, 4369.

11) I. Verona , J. P. Gutheil , R. D. Pike and G. B. Carpenter, “Regioselectivity in the Nucleophilic Functionalization of Dibenzofuran, Dibenzothiophene and Xanthene Complexes of Mn(CO) 3+”, Journal of Organometallic Chemistry 1996 , 524, 71.

10) S. Sun, L. K. Yeung, D. A. Sweigart, T.-Y. Lee, S. S. Lee, Y. K. Chung, S. R. Switzer and R. D. Pike, “( h6 -Polyarene)Mn(CO)3+ Complexes as Manganese Tricarbonyl Transfer Reagents. A Convenient and General Synthetic Route to (Arene)Mn(CO) 3+ Complexes”, Organometallics 1995, 14, 2613.

9) W. H. Starnes, Jr., H. Chung, R. D. Pike, B. J. Wojciechowski, V. G. Zaikov, G. M. Benedikt and L. F. Rhodes, “The Reaction of Macroradicals with Alkene Chain Ends During the Polymerization of Vinyl Chloride” Polymer Preprints (American Chemical Society, Division of Polymer Chemistry) 1995, 36, 404.

8) C. C. Carson, R. D. Pike, and G. B. Carpenter, “Azidotetrakis(trimethylphosphine)nickel(II) Tetrafluoroborate”, Acta Crystallographica, Section C 1995, 51, 595.

7) R. D. Pike, “Benzene(cyclopentadienyl)iron Hexafluorophosphate ” In Encyclopedia of Reagents for Organic Synthesis ; L. A. Paquette, Ed.; Wiley: Chichester , U.K. , 1995; pp. 242-244.

6) R. D. Pike, “Disodium Tetracarbonylferrate” In Encyclopedia of Reagents for Organic Synthesis ; L. A. Paquette, Ed.; Wiley: Chichester , U.K. , 1995; pp. 2299-2301.

5) J. D. Jackson, S. J. Villa, D. S. Bacon, R. D. Pike, and G. B. Carpenter, “Arene(tricarbonyl)manganese(I) Complexes, A Preparative Study. Crystal Structure of [( h6-C6H5CH2 COCH 2Ph)Mn(CO)3]BF4”, Organometallics 1994, 13, 3972.

4) R. D. Pike, “Metal-Alkyl and Metal-Hydride Bond Formation and Fission” In Mechanisms of Inorganic and Organometallic Reactions , Vol. VIII; M. V. Twigg, Ed.; Plenum Press: New York , 1994; pp. 261-281.

3) T.-Y. Lee, Y. K. Kang, Y. K. Chung, R. D. Pike, and D. A. Sweigart,  “Manganese-Mediated Synthesis of cis-Disubstituted Cyclohexadienes Via Double Nucleophilic Addition to Coordinated Arenes”, Inorganica Chimica Acta 1993 , 214, 125.

2) R. D. Pike, H. Cui, R. Kershaw, K. Dwight, A. Wold, T. N. Blanton, A. A. Wernberg, and H. J. Gysling, “Low Temperature Preparation of Zinc Sulfide Thin Films by Ultrasonic Spray Pyrolysis from bis(Diethyldithiocarbamato)zinc(II)”, Thin Solid Films 1993, 224, 221.

1) R. D. Pike and G. B. Carpenter, “Dicarbonyl(isocyanide)(arene)manganese Cations, Preparation and Nucleophilic Addition Reactions. The Molecular Structure of [(h 6 -C6(CH3)6)Mn(CO) 2(CNMe)][O 3SCF3]”, Organometallics 1993, 12 , 1416.